Electrochemical Oxidative Cross-Coupling Reaction to Access Unsymmetrical Thiosulfonates and Selenosulfonates

Zhang, XF (Zhang, Xiaofeng)[ 1 ] ; Cui, T (Cui, Ting)[ 1 ] ; Zhang, YH (Zhang, Yanghao)[ 1 ] ; Gu, WJ (Gu, Weijin)[ 1 ] ; Liu, P (Liu, Ping)[ 1 ]*（刘平）; Sun, PP (Sun, Peipei)[ 1 ]*（孙培培）

[ 1 ] Nanjing Normal Univ, Coll Chem & Mat Sci, Jiangsu Collaborat Innovat Ctr Biomed Funct Mat, Jiangsu Prov Key Lab Mat Cycle Proc & Pollut Cont, Nanjing 210023, Jiangsu, Peoples R China

ADVANCED SYNTHESIS & CATALYSIS，201904,361(9),2014-2019

The electrochemical oxidative cross-dehydrogenative coupling of arylsulfinic acids with thiophenols was achieved via a radical process. A wide range of arylsulfinic acids and substituted thiophenols were found to be tolerated, providing unsymmetrical thiosulfonates in good to excellent yields. This electrochemical method can also be used for the reaction of arylsulfinic acids with disulfides or diselenides to obtain thiosulfonates or selenosulfonates.

文章链接：

https://onlinelibrary.wiley.com/doi/full/10.1002/adsc.201900047

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