[ 1 ] Nanjing Normal Univ, Jiangsu Collaborat Innovat Ctr Biomed Funct Mat, Sch Chem & Mat Sci, Jiangsu Key Lab New Power Batteries, Nanjing 210023, Peoples R China
[ 2 ] Sichuan Univ, Coll Chem, Chengdu 610064, Peoples R China
CHEMICAL COMMUNICATIONS 2020,56, 15667-15670
Highly branched PdP nanosheets (NSs) rich in defects and with a thickness of similar to 3.2 nm were synthesized, for the first time, via a nanoconfined attachment growth mechanism inside assembled lamellar micelles. Owing to the synergistic structural (being a highly branched, ultrathin, and defect-rich material) and compositional (P-alloyed) advantages, the PdP NSs exhibited remarkable electrocatalytic activity (3.2 A mg(Pd)(-1)), a low reaction activation energy (16.0 kJ mol(-1)), good CO anti-poisoning ability, and electrocatalytic stability during the ethanol oxidation reaction (EOR) in alkaline conditions.
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